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    • 专利摘要:
    An ink composition for continuous flow jet printing, liquid at room temperature, comprising: a) a solvent comprising, preferably consisting of, one or more organic solvent (s) and optionally some water ; b) a binder, comprising at least one polyester resin prepared by polymerization of terephthalic acid, isophthalic acid, neopentyl glycol, and ethylene glycol; c) optionally, one or more dye (s) and / or pigment (s). A method of marking a substrate, support or object by projecting onto a surface of said substrate, support, or object of this ink composition. Substrate, carrier, or article, especially bottle, bottle, tray, stopper, cable or pipe made of polyolefin, for example polyethylene or polypropylene, provided with a mark obtained by drying, and / or absorption in the substrate, support, or object, of this ink composition.
    公开号:FR3033572A1
    申请号:FR1552078
    申请日:2015-03-13
    公开日:2016-09-16
    发明作者:Cecile Goustiaux；Antoine Bataille；Yannick Jean
    申请人:Dover Europe SARL；
    IPC主号:
    专利说明:

    [0001] 1 INK COMPOSITION FOR CONTINUOUS JET PRINTING IN PARTICULAR ON ORGANIC POLYMER SUBSTRATES. DESCRIPTION The invention relates to an ink composition whose properties are particularly well suited to marking or printing by liquid jet, and particularly to continuous deviated ink jet marking. The ink composition according to the invention can be used for marking substrates, substrates and objects of all kinds. The ink composition according to the invention is particularly suitable for marking substrates, supports and articles made of organic polymers, in particular thermoplastic polymers ("plastics"), such as polyolefins such as polyethylenes (PE) or polypropylenes ( PP), or poly (ethylene terephthalate) (PET). The ink composition according to the invention is particularly suitable for marking bottles, packaging, bottles or trays made of organic polymers, in particular polyolefins, such as polyethylenes or polypropylenes. An opaque variant, for example white or light-colored, of the ink composition according to the invention is also suitable for marking black or dark substrates, for example for marking black or colored tubes and cables. dark. The ink composition according to the invention makes it possible to obtain markings which are resistant in particular to friction and to common solvents such as ethanol, and adhesives, that is to say, successfully undergoing the peel test 25 adhesive. Inkjet printing is a well known technique, which allows the printing, marking, or decoration of all kinds of objects, at high speed, and without contact of these objects with the printing device, variable messages at will, such as barcodes, sales deadlines, etc. even on non-planar supports. 3033572 2 Inkjet printing techniques are divided into two main types, namely: the technique known as "drop on Dernand" (or "DOD" in English), and the technique known as "Continuous Ink Jet" ("Cil" in English). We will focus more particularly on this last technique, more precisely on the deviated continuous jet technique. The deflected continuous jet projection consists in sending ink under pressure into a cavity containing a piezoelectric crystal, from which the ink escapes through an orifice (nozzle) in the form of a jet.
    [0002] The piezoelectric crystal, vibrating at a specific frequency, causes pressure disturbances in the ink jet, which oscillates and gradually breaks up into spherical drops or droplets. An electrode, placed in the path of the jet, where it breaks, makes it possible to give these drops an electrostatic charge, if the ink is conductive. The drops thus charged are deflected in an electric field and allow printing. The uncharged drops, therefore not deflected, are recovered in a gutter where the ink is sucked and then recycled to the ink circuit. This type of jet ink projection ensures high speed non-contact marking of scrolling on non-planar objects and with the possibility of changing messages at will. The technique is particularly suitable for marking and identification (expiry dates, serial numbers, batch numbers, barcodes etc.), industrial products on the production lines. The ink compositions, suitable for projection, printing, by the deviated continuous jet technique, must satisfy a certain number of criteria inherent to this technique, relating, inter alia, to the viscosity, the electrical conductivity, the solubility in a solvent for cleaning, the compatibility of the ingredients, the correct wetting of the media to be marked, etc. Particular and important criteria to be satisfied by ink compositions for printing by the deviated continuous jet technique, 3033572 3 are on the one hand because the ink consumption is low when the number of characters printed per message is low, and secondly because the jet is continuous and the ink recirculates many times before being projected. As a result, the ink is in contact with the ambient air during the suction of the non-deflected drops, and it can be made to absorb the ambient humidity or to react with the oxygen of the air, and may be so modified. Despite this situation, the ink will retain its essential properties both during storage and during circulation in the printer. Finally, these inks must dry quickly, be able to pass through the nozzle 10 without clogging, with a great stability of orientation of the jet while allowing easy cleaning of the print head. The ingredients that make up the current inks, for the deviated continuous jet type ink jet, are organic or mineral products; they are dyestuffs, such as dyes or pigments, resins or binders, in one or more volatile solvent (s) or in water, optionally a salt or salt ( s) conductivity, as well as various additives. The dyestuffs are called "dyes or pigments", depending on whether they are respectively soluble or insoluble in the solvent used. Pigments, which are inherently insoluble, are therefore dispersed and may be opaque or non-opaque. They bring to the ink its color, its opacity, or particular optical properties, such as fluorescence (see US Pat. Nos. 4,153,593, 4,756,758 and 4,880,465, US Pat. A-0 289 141, US-A-5,395,432, GB-A-2,298,713). In some cases, the dyes also provide sufficient ink conductivity so that there is no need to add a conductivity salt. The dyes known under the name C.I. Solvent Black 27, 29, 35 and 45 are in this case. The binder (s) or resin (s) is (are) generally for the most part solid (s) and polymeric compound (s) and their choice is dictated by their solubility in the selected solvents and by their compatibility with dyes and other additives, but also and especially according to the properties they bring to the ink film, once dry (see US Patent Nos. 4,834,799; A-2,286,402, US-A-5,594,044, US-A-5,316,575, WO-A-96/23844, WO-A-95/29287). Their primary function is to provide the ink with adhesion on the maximum of supports or on specific supports, for example non-porous. They also make it possible to give the ink the appropriate viscosity for the formation of the drops from the jet and they bring to the ink, or rather to the marking obtained, most of its properties of resistance to physical and / or chemical attack. especially resistance to rubbing, peeling by adhesive tape ("Scotch®"), or resistance to other common solvents such as ethyl alcohol.
    [0003] The solvent of these inks is most frequently a mixture comprising, on the one hand, a major amount of volatile and low-viscosity solvents, in order to allow the labels to be dried very quickly and to adjust the viscosity to the desired value. 2 to 10 mPa.s and, on the other hand, more viscous and less volatile solvents with slower drying, in a lesser amount, to avoid drying of the ink in the nozzle during the phases. stopping the printing apparatus (see US Patent Nos. 4,155,767, WO-A-92,14794, WO-A-92,147,55 and US-A-4,260,531). The volatile solvents most often used are alcohols, ketones or low molecular weight esters as disclosed in US-A-4,567,213 and US-A-5,637,139. Among these solvents, mention may be made essentially of methanol, ethanol, 1- and 2-propanol, acetone, methyl ethyl ketone ("MEK"), methyl isobutyl ketone, ethyl acetate, and tetrahydrofuran. The less volatile solvents having in particular a function of retarding drying are most often ketones, such as cyclohexanone, glycol ethers, cited in US-A-4,024,096 and US-A-4,567,213, the ethers and the acetals, such as furan or dioxane, mentioned in US-A-4,155,767, dimethylformamide or dimethylsulfoxide (US-A-4,155,895), lactones (EP-A-0 034 881), N-methyl pyrrolidone (EP-A-0 735 120), glycols (WO-A-96 23844), and even aliphatic hydrocarbons (US-A-4,166,044) or still water alone or in combination with other solvents , cited above, reference will be made to US-A-4,153,593, GB-A-2,277,094 and FR-A-2,460,982. In general, the main or majority solvents of the inks for deviated continuous jet projection must meet a number of criteria, in particular: their volatility must be sufficient for the ink dries quickly on the medium to be marked, but not too large, so as not to evaporate too quickly in the printer, especially during shutdowns; their solvent power, vis-à-vis the binders of the ink, dyes or pigment dispersions and vis-à-vis the printing media, must allow to give the dry ink, a good adhesion; their effects on human health, namely their toxicity, harmfulness, irritancy and flammability, must be reduced; they must make it possible to maintain sterile ink possibly intended to be ingested; finally, they must have the capacity to maintain dissolved and dissociated ionic species such as salts that give the ink its electrical conductivity. The salt (s) of any conductivity (s) provide the ink with the conductivity necessary for the electrostatic deflection. In this regard, reference may be made to US-A-4,465,800. The additives include dispersants which allow the dispersion of pigments, surfactants which modify the wetting or penetrating power of the ink (US-A-5,395,431), in particular those which modify or regulate the static or dynamic surface tension, such as Fluorad® FC 430 from the company 3M®, the agents which inhibit the corrosion induced by the salts which bring the conductivity mentioned above (see EP-A-0 510 752, US-A-5,102,458), or the additives which protect the ink against the proliferation of bacteria and other micro-organisms: these are biocides, bactericides, fungicides and the like, particularly useful in the 63 inks containing water, the pH-regulating buffers ( see EP-A-0 735 120), anti-foam agents. Moreover, it is known that the traceability of products such as food, pharmaceutical or medical products requires that various information be printed on the packaging of these products. The affixing of markings on beverage bottles, or packaging of cosmetic products, and in particular on plastic caps or bottles, for example made of polyolefins and in particular polyethylene, poses particularly difficult problems to solve, particularly in the where the markings must not only withstand the liquids contained in these packages, but also the inevitable friction of the user. In order to guarantee the traceability of the production, the bottles are generally marked on the cap or on the bottom of the bottle, or at any other place, with corresponding information, immediately after filling.
    [0004] The deviated continuous ink jet technology is with CO2 laser marking the most appropriate technique for this high-speed marking on these curved surfaces of variable information. For such applications, the ink for deviated continuous jet printing and the deposited marking must meet particular requirements, which include the following: the ink must dry very rapidly when the production rates are high; the marking must withstand the manipulation by the consumer during the entire period of consumption of the contents of the packaging, such as a bottle; The marking must withstand the liquids contained in the packages such as alcoholic solutions; marking must be resistant to friction; the marking must be adherent.
    [0005] In order to test the adhesion of the markings, the adhesive tape test called "Scotch test" is very commonly applied. It consists of applying an adhesive to the marking and removing the adhesive. The test is positive when the marking remains on the object and is not transferred to the adhesive. To obtain a satisfactory adhesion and also a satisfactory resistance of the markings obtained with the ink jet ink compositions on the substrates, such as packaging, made of organic polymers, in particular of plastics, and in particular on the polyolefin substrates for example polyethylenes or polypropylenes, it is currently necessary to perform a surface treatment of the substrate such as a buckling treatment or a corona treatment, and / or to include in the ink composition halogenated compounds, especially chlorinated compounds, resins based on vinyl chloride. There is therefore a need for an ink composition for printing by the deviated continuous jet technique which gives markings exhibiting in particular satisfactory, even improved, adhesion over known ink compositions on substrates, such as that cables, pipes or packaging, made of organic polymers, in particular, plastics, and in particular on substrates made of polyolefins, for example polyethylenes or polypropylenes, without it being necessary to perform a surface treatment of the substrate , such as a buckling treatment or a corona treatment, and / or including in the ink composition halogenated, especially chlorinated compounds, such as vinyl chloride resins. There is, in particular, a need for ink compositions for printing by the continuous deviated jet technique which gives markings having an adhesion (generally determined by the so-called "adhesive tape" test) satisfactory, or even improved relative to the known ink compositions, on said substrates, but which are free of halogenated compounds, especially chlorinated compounds, such as resins based on vinyl chloride, these ink compositions also making it possible to obtain more resistant markings, especially friction and alcohol.
    [0006] The object of the invention is to provide an ink composition suitable for continuous deviated jet printing, which meets, inter alia, all the needs, requirements and criteria indicated above, and which does not present not the disadvantages, limitations, disadvantages and disadvantages of the prior art ink compositions, and overcomes the problems of the prior art ink compositions. This and other objects are achieved in accordance with the invention by an ink composition for continuous liquid temperature deviated jet printing comprising a) a solvent comprising, preferably consisting of, a or more organic solvent compound (s), and optionally water; b) a binder, comprising at least one polyester resin prepared by polymerization of terephthalic acid, isophthalic acid, neopentyl glycol, and ethylene glycol; c) optionally, one or more dye (s) and / or pigment (s). By "ambient temperature" is generally meant a temperature of 5 ° C to 30 ° C, preferably 10 ° C to 25 ° C, more preferably 15 ° C to 24 ° C, more preferably 20 ° C to 23 ° C. ° C. It is understood that the ink is liquid at atmospheric pressure. Advantageously, said ink composition is free of halogenated compounds. By "free from halogenated compounds" is generally meant that the ink composition according to the invention comprises less than 0.1% by weight, or even 0% by weight of the total weight of the ink composition, of halogenated compounds. The ink composition according to the invention is especially free of chlorinated compounds, such as vinyl chloride resins such as polyvinyl chloride (PVC). The ink composition according to the invention is fundamentally different from ink compositions according to the prior art in that it comprises a binder, comprising at least one polyester resin, which is a very specific resin prepared by polymerization of four specific monomers, namely terephthalic acid, isophthalic acid, neopentyl glycol and ethylene glycol. Incorporation of such a polyester resin into the binder of an ink composition suitable for deviated continuous jet printing is neither described nor suggested in the prior art. This polyester resin is specific in that it is prepared from 4 specific monomers, namely two specific diacids and two specific diols, all these monomers being present in the polymerization mixture and then forming the polyester resin.
    [0007] These polyester resins prepared from two diacids and two diols are amorphous and therefore soluble in organic solvents, in contrast to crystalline polymers which are insoluble in organic solvents. A polyester resin which can be included in the composition according to the invention is, for example, the resin available under the name of Vylon GK 250® from Toyobo Vylon. This polyester is indeed a copolymer of at least the two aforementioned diacids, namely terephthalic acid and isophthalic acid with at least the two diols mentioned above, namely neopentyl glycol and ethylene glycol. The ink composition according to the invention meets, inter alia, the needs and requirements mentioned above, and provides a solution to the problems of the prior art ink compositions. According to the invention, it has been found, in a surprising manner, that the presence in the binder of the ink composition according to the invention of the specific polyester resin described above makes it possible to obtain ink compositions for printing. by ink jet by the deviated continuous jet technique which give markings whose adhesion (generally determined by the so-called "adhesive tape" test), on organic polymers, in particular, plastics, and in particular on the polyolefins, for example polyethylenes or polypropylenes, is greater than that of the markings obtained with the ink compositions of the prior art, and this without it being necessary to subject the substrate to a surface treatment beforehand 3033572 and optionally including halogenated compounds, such as vinyl chloride resins, in the ink composition. The ink compositions according to the invention, the binder of which comprises the specific polyester resin described above, also make it possible, surprisingly, to obtain more resistant markings, in particular with respect to friction and to alcohol in particular, on polymers. organic materials, especially plastics, and in particular polyolefins, for example polyethylenes or polypropylenes, than labels obtained with prior art ink compositions which do not comprise a binder containing the specific polyester resin described above. high.
    [0008] It was not evident from the known ink compositions that the use in the binder of the specific polyester resin described above could give the markings a particularly good adhesion, particularly to organic polymer substrates, especially plastics, and in particular polyolefins, for example polyethylenes or polypropylenes, as well as excellent resistance to friction and solvents such as ethanol; this particularly good adhesion as well as this excellent resistance to friction and solvents being better than the adhesion and the resistance to friction obtained with ink compositions which do not include said specific polyester resin.
    [0009] Advantageously, the binder of the ink composition according to the invention may further comprise a resin derived from rosin. The resin derived from rosin may be an ester of glycerin and rosin, for example the Bremasin®1380 resin from Kraemer®. In this case, where the binder of the ink composition according to the invention further comprises a resin derived from rosin, the binder of the ink composition according to the invention is a very specific binder which comprises a combination of two specific compounds namely the combination of a polyester resin, and a rosin-derived resin which has never been described or suggested in the prior art. Advantageously, the binder of the ink composition according to the invention may further comprise a polyol resin.
    [0010] By polyol resin is meant a resin having hydroxyl groups, OH, free. The polyol resin may be a hydrogenated copolymer of acetophenone and formaldehyde, such as Variplus SK® resin from Tego®. In this case where the binder of the ink composition according to the invention further comprises a polyol resin, the binder of the ink composition according to the invention, is a very specific binder which comprises a combination of two compounds specific to namely the combination of a polyester resin, and a polyol resin which has never been described or suggested in the prior art.
    [0011] The binder of the composition according to the invention may comprise both the specific polyester resin described above, the resin derived from rosin, and the polyol resin. An ink composition for deviated continuous jet printing whose binder comprises the combination of these three specific resins has never been described or suggested in the prior art. The ink composition according to the invention when it comprises a binder which comprises the specific polyester as described above and furthermore a resin derived from rosin or a polyol resin, meets a fortiori, inter alia, the needs and requirements mentioned above, and provides a solution to the problems of the ink compositions of the prior art. According to the invention, it has been found, in a surprising way, that the specific combination of two specific compounds in the binder, namely the specific polyester resin described above, and a resin derived from rosin or a polyol resin, made it possible to obtain ink compositions for inkjet printing by the deviated continuous jet technique which give markings whose adhesion (generally determined by the so-called "adhesive tape" test) on organic polymers, especially plastics, and in particular polyolefins, for example polyethylenes or polypropylenes, is greater than that of the markings obtained with the ink compositions of the prior art, but also generally that of the markings obtained with the ink compositions of which the binder comprises only the above-mentioned specific polyester resin, and this without it being necessary to submit previously the substrate to a surface treatment and optionally include halogenated compounds, such as vinyl chloride resins, in the ink composition. The ink compositions according to the invention, the binder of which comprises the combination of the specific polyester resin described above, and a resin derived from rosin or from a polyol resin, also make it possible, surprisingly, to obtain more resistant markings, especially to rubbing and alcohol in particular, on organic polymers, in particular plastics, and in particular on polyolefins, for example polyethylenes or polypropylenes, than the markings obtained with the compositions of ink of the prior art, but also generally as the markings obtained with the ink compositions whose binder comprises only the above-mentioned specific polyester resin. It was not obvious from the known ink compositions that the combination of the two types of binder mentioned above could provide the markings with particularly good adhesion and further improvement over the ink compositions of which the binder does not comprise whereas the above-mentioned specific polyester resin, in particular on organic polymer substrates, in particular plastics, and in particular polyolefins, for example polyethylenes or polypropylenes, as well as an excellent resistance and further improved with respect to ink whose binder comprises only the above-mentioned specific polyester resin to rubbing and solvents such as ethanol. The ink composition according to the invention when it comprises a binder which comprises the specific polyester as described above and furthermore a resin derived from rosin and a polyol resin, that is to say the three abovementioned resins , a fortiori, meets, among others, the needs and requirements mentioned above, and provides a solution to the problems of ink compositions of the prior art. The ink composition for ink jet printing by the deviated continuous jet technique according to the invention when the binder comprises the specific combination of the three specific resins mentioned above, namely the polyester resin, the resin derivative of rosin and the polyol resin, makes it possible to obtain, surprisingly, markings whose adhesion and resistance, in particular to friction, are further improved with respect to the ink compositions whose binder contains only the polyester resin or the polyester resin combined with a resin derived from rosin or a polyol resin. It was not obvious from the known ink compositions that the combination of the 3 types of resins mentioned above could give the markings particularly good adhesion, and still improved, especially on organic polymer substrates, especially plastics, and in particular polyolefins, for example polyethylenes or polypropylenes, as well as excellent resistance and further improved friction and solvents such as ethanol. Thus, US-A-4,207,577 discloses opaque ink compositions for inkjet printing which comprise resins. Among the many resins mentioned are incidentally mentioned polyester resins and rosin resins in general. The exact nature of these polyester resins is not specified. In particular, the very specific polyester resin of the binder of the ink composition according to the invention is neither described nor suggested in this document. In addition, the particular combination of one of the binder-specific polyester resin of the ink composition according to the invention with a rosin resin and / or a polyol resin is in no way described or suggested in this invention. document.
    [0012] In addition, the ink composition of this document may also include chlorinated resins such as polyvinyl chloride, polyvinylidene chloride and chlorinated rubbers. US-B2-7,022,172 relates to an ink composition for inkjet printing which comprises in particular a resin and a dispersant.
    [0013] Among the many resins mentioned are incidentally cited rosin resins. The dispersant is in particular a polyester amine. There is no mention or suggestion in this document that the ink composition described therein may comprise a polyester, let alone the very specific polyester present in the ink composition according to the invention, combination with a rosin resin. There is no further mention or suggestion in this document that the ink composition described therein may further comprise a polyol resin such as that advantageously present in the ink composition according to the present invention. invention. In addition, the ink composition of this document may include chlorinated resins such as vinyl chloride-acetate resins. US-B2-7,132,014, US-B2-7,132,013, and US-B2-7,014,698 relate to pigment ink inkjet printing compositions which contain a pigment, a polymer, and a solvent. organic composition comprising a poly (alkylene glycol) derivative and a nitrogen heterocyclic compound. The polymer may be a binder resin selected from acrylic resins, polyester resins, polyurethane resins, vinyl chloride resins and cellulosic resins. The exact nature of the polyester resin is not specified and there is no mention or suggestion in these documents that this polyester resin may be a specific polyester resin such as that present in the ink composition according to the present invention. invention. There is further no mention or suggestion in these documents that the ink compositions described therein may further comprise a rosin-derived resin such as that advantageously present in the ink composition according to the present invention. invention. There is no further mention or suggestion in these documents that the ink compositions described therein may further comprise a polyol resin such as that advantageously present in the ink composition according to the invention.
    [0014] In addition, the ink compositions of these documents may include vinyl chloride resins. According to a fundamental aspect of the invention, the ink compositions according to the invention give markings, resistant to friction, resistant to the adhesive tape test ("Scotch ®"), and to the rubbing in the presence of alcohol. Preferably, the ink compositions according to the invention do not contain a chlorinated compound such as resins based on vinyl chloride. Advantageously, the ink composition according to the invention may comprise from 0.1% to 30% by weight, preferably from 5% to 20% by weight, of the total weight of the ink composition, of the polyester resin . Advantageously, the ink composition according to the invention may comprise from 0.1% to 20% by weight, preferably from 1% to 15% by weight, of the total weight of the ink composition, of the resin derived from rosin.
    [0015] Advantageously, the ink composition according to the invention may comprise from 0.1% to 25% by weight, preferably from 2% to 10% by weight, of the total weight of the ink composition, of the polyol resin. . The binder may comprise only the polyester resin, optionally the resin derived from rosin, and / or optionally the polyol resin, that is to say that the binder 20 is then constituted by the polyester resin and, optionally, by the resin derived from rosin and / or optionally by the polyol resin. Thus the binder can consist solely of the polyester resin; only by the polyester resin and the resin derived from rosin; only by the polyester resin and the polyol resin; or only by the polyester resin, the rosin-derived resin and the polyol resin. Among the compositions in which the binder consists of the polyester resin, the rosin-derived resin and the polyol resin, the preferred compositions are those in which the proportions by weight of the various resins relative to the total weight of the binder, in other words relative to the total weight of all the resins 3033572 16 are as follows: 30% to 60% of the polyester resin, 20% to 50% of the rosin-derived resin, and 15% to 40% of the polyol resin. Within the restricted range defined by these narrow weight percentage ranges of each of the resins relative to the total weight of the binder, the properties of the markings obtained with the ink compositions according to the invention are optimal, in particular the adhesion especially on polyethylene and polypropylene markings and their resistance, including alcohol, are optimal. Or the binder may comprise, in addition to the polyester resin, the rosin resin, one or more other polymers and / or resins.
    [0016] Advantageously, this or these other polymer (s) and / or resin (s) may be chosen from (meth) acrylic, vinyl, ketone, hydroxyaromatic, cellulosic, styrene, epoxy, polyurethane resins, styrene acrylates, alkoxysilanes, and combinations of two or more thereof. Advantageously, the binder is from 1% to 45% by weight, preferably from 5% to 30% by weight, more preferably from 10% to 20% by weight, of the total weight of the ink composition according to the present invention. invention. The ink composition according to the invention comprises a very small amount of water, generally less than 10% by weight, preferably less than 5%, more preferably less than 1% by weight, relative to the total weight of the ink composition. The ink composition according to the invention can even be considered as essentially free from water (0% water). In fact, the water present is only the water supplied as an impurity in the various components of the ink. The greater the degree of purity of the selected components, the lower the water content. The low content or absence of water in the ink composition according to the invention promotes the formation of the ink film when the binders and other dyes in the composition are insoluble in water, thus improving the strength and adhesion of the ink.
    [0017] In the composition according to the invention, the solvent generally represents at least 20% by weight of the total weight of the ink composition, preferably the solvent represents from 30% to 90% by weight, more preferably 60% by weight. at 80% by weight, of the total weight of the ink composition. The solvent comprises, preferably consists of, one or more organic solvent compound (s) and optionally water provided that the amount of water meets the conditions indicated above. Advantageously, the one or more organic solvent compound (s) comprises (comprise) a majority proportion by weight, relative to the total weight of the solvent (50% by weight of the total weight of the solvent or more, or even 100% by weight of the total weight of the solvent), of one or more volatile organic solvent compound (s), and a minor proportion by weight, relative to the total weight of the solvent, one or more nonvolatile organic solvent (s) compound (s). Preferably the solvent is one or more volatile organic compound (s). By "volatile organic solvent compound" is generally meant that this compound has an evaporation rate greater than 0.5 on the scale where the butyl acetate has an evaporation rate of 1. The compound or compounds ( s) organic solvent (s) forming part of the solvent is (are) chosen from, for example, alcohols, in particular low molecular weight alcohols, for example aliphatic alcohols such as ethanol; ketones preferably of low molecular weight; alkylene glycol ethers; esters of alkylene glycols and esters of alkylene glycol ethers, such as acetates; dimethylformamide; N-methyl pyrrolidone; acetals; esters; linear or cyclic ethers; aliphatic, cyclic or linear hydrocarbons; aromatic hydrocarbons; and carbonates such as propylene carbonate, ethylene carbonate and dimethyl and diethyl carbonates; and their mixtures. Preferably, this or these solvent compound (s) possess the property of dissolving the other ingredients of the ink, especially the binder, the dyestuffs, the additives, and the like.
    [0018] The alcohols will preferably be chosen from linear or branched aliphatic alcohols containing from 1 to 8 carbon atoms, such as methanol, ethanol, propanol-1, propanol-2, n-butanol, butano1-2, tert-butanol, etc. The ketones will preferably be chosen from ketones of 3 to 10 carbon atoms, such as acetone, butanone (methyl ethyl ketone), pentanone 2 (methyl propyl ketone), methyl 3 butanone-2 (methyl-isopropyl ketone) and methyl-4-pentanone-2 (methyl isobutyl ketone). The alkylene glycol ethers are preferably selected from monoalkyl (C1-C6 alkyl) or dialkyl (C1-C6 alkyl) ethers of alkylene glycol having 1 to 10 carbon atoms in the alkylene chain, from preferably it is ethylene ethers or propylene glycol, such as methoxy-propanol. The alkylene glycol esters and the alkylene glycol ether esters are preferably selected from the esters thereof with saturated aliphatic carboxylic acids having from 1 to 6 carbon atoms, such as formic acid, acetic acid, propionic acid, butyric acid, valeric acid and caproic acid. Examples include methoxypropyl acetate, butyldiglycol acetate, and the like. The esters are preferably selected from low molecular weight esters such as the formates, acetates, propionates or butyrates of alcohols of 1 to 10 carbon atoms. The acetals are preferably selected from low molecular weight acetals such as ethylal and methylal. The ethers are preferably selected from low molecular weight ethers such as dioxolane or tetrahydrofuran. Those skilled in the art will be able to easily identify, among these volatile compounds, those which are volatile and those which are non-volatile. A preferred solvent according to the invention comprises a major amount by weight relative to the total weight of the solvent, preferably consists of one or more solvent (s) chosen (s) from ketones from 3 to 10 carbon atoms, such as acetone, butanone (methyl-ethyl-ketone or MEK), pentan-2-one (methyl-propyl-ketone), methyl-3-butanone-2 (methyl-isopropyl ketone) and methyl-4-pentanone-2 (methyl isobutyl ketone or MIK). A particularly preferred solvent comprises a major amount by weight relative to the total weight of MEK solvent, preferably consists of MEK. This preferred solvent may additionally comprise one or more other solvent compound (s) other than the ketone (s) in a total minor amount by weight, relative to the total weight of the solvent, for example in an amount from 0.1% to 20% by weight, preferably from 5% to 15% by weight, based on the total weight of the solvent, in order to optimize the properties of the inks. These minor solvents may be chosen from esters, ethylene glycol or propylene glycol ethers, and acetals. The dye (s) and / or pigment (s) may be chosen from all the dyes or pigments that are suitable for the intended use, known to those skilled in the art, some of these pigments or dyes have already been mentioned above. Dyestuffs and pigments will generally be chosen from the dyes and pigments known under the name "C. I. Solvent Dyes" and "C. I. Pigments". By way of example, the most common pigments and dyes include C.I. Solvent Black 7, C.1. Solvent Black 29, C.1. Solvent Black 27, C.1. Solvent Black 28, C.
    [0019] I. Solvent Black 35, C.I. Solvent Blue 45, C.I. Solvent Blue 70, C.I. Solvent Red 124, dispersions of Pigment Blue 60, Pigment Black 7, Pigment White 6 or Pigment Blue 15; or fluorescent dyes and optical brighteners. Pigments also include lacquers. When it is desired that the labels obtained with the ink composition according to the invention are water-resistant, a dye with the lowest solubility in water, which is insoluble in water, should preferably be selected. 'water. By "water insoluble dye" is generally meant a dye which, added to 1% in demineralised water, does not cause discoloration of water visible to the eye.
    [0020] Advantageously, the dye (s) is (are) chosen from organic dyes soluble in ketones. Advantageously, the pigment (s) may be chosen from carbon blacks, titanium oxides, and mixtures thereof. A preferred colorant is C.I. Solvent Black 27. The ink composition may be black or dark in color. Such a composition contains, for example, as a dye of Solvent Black 27. Such a composition will give a black or dark color marking and is therefore particularly suitable for marking white or light-colored substrates. Alternatively, the ink composition may be opaque, preferably white or light in color. Such an opaque composition contains, for example as a pigment, a TiO 2 titanium oxide. Such a composition will give a white or light color marking and is therefore particularly suitable for marking black substrates or dark color such as cables or pipes. The total amount of dye (s) and / or pigment (s) is generally from 0.05% to 25% by weight, preferably from 1% to 20% by weight, more preferably from 3% to 10% by weight. % by weight, of the total weight of the ink composition. The ink composition may, in addition, comprise one or more plasticizers (of the resin (s) or polymer (s) or compound (s) of the binder) chosen, for example, from the known plasticizers of those skilled in the art and chosen according to the binder used 25 comprising one or more polymer (s) and / or resin (s), mention may be made, as a plasticizer, for example, thermoplastic polyurethanes, phthalates, adipates citrates and esters of citric acid, alkyl phosphates, glycerol, lactic acid, oleic acid, polypropylene glycol, triglycerides of fatty acids, levulinic acid; and their mixtures.
    [0021] The plasticizer (s) is (are) generally present in a proportion of at least 0.05% by weight, preferably from 0.1% to 20% by weight, of the total weight of the composition. ink. The ink composition according to the invention may, in addition, possibly comprise at least one conductivity salt. Indeed, the ink composition according to the invention being applicable by deviated continuous jet, it must have a sufficient electrical conductivity generally greater than 5 μS / cm at 20 ° C, preferably greater than or equal to 300 μS / cm at 20 ° C. ° C, more preferably greater than or equal to 500 uS / cm at 20 ° C.
    [0022] The conductivity of the ink composition according to the invention may for example be from 5 to 5000 μS / cm at 20 ° C., in particular from 500 to 2000 μS / cm at 20 ° C. The products providing the ink with the conductivity necessary for continuous jet projection are ionizable compounds, such as salts. It is possible that dyes, pigments, or other ingredients of the ink are themselves salts and give sufficient conductivity to the ink so that there is no need to add salt therein. conductivity itself: this is particularly the case of the compounds known under the name "CI Solvent Black 27, 29, 35 and 45", already mentioned. However, it will often be necessary to include in the ink composition, in addition, a salt of different conductivity dyes, pigments and other ingredients.
    [0023] By "conductivity salt" is meant a salt that provides electrical conductivity to the ink composition. This salt (s) of conductivity is (are) generally chosen from alkaline, alkaline-earth metal and simple or quaternary ammonium salts, in the form of nitrates, thiocyanates, formates, acetates, sulfates, propionates, hexafluorophosphates, hexafluoroantimonates etc. When the markings obtained with the ink composition must be water-resistant, one or more of these water-insoluble (i.e., generally, solubility-soluble water is less than 0.5% by weight), such as fatty-chain quaternary ammoniums and hexafluorophosphates or hexafluroantimonates.
    [0024] This conductivity salt (s) will (if) therefore be present (s), if necessary, in the ink composition so as to impart the above conductivity to the ink, generally in the form of at least 0.05% by weight, preferably from 0.1% to 20% by weight, more preferably from 0.1% to 10% by weight, and more preferably from 0.1% to 5% by weight, total weight of the ink composition. The composition according to the invention may, in addition, comprise one or more additive (s) chosen (s) from the compounds which improve the solubility of some of these components, the print quality, the adhesion, or the control wetting the ink on different media.
    [0025] The additive (s) may be selected from, for example, antifoam agents; chemical stabilizers; UV stabilizers; surfactants, such as Fluorad® FC 430 or Byk® 333; agents inhibiting corrosion by salts such as conductivity salts; bactericides, fungicides and biocides; and pH buffers, etc.
    [0026] The additive (s) are (are) used at very low doses, generally less than or equal to 5% and sometimes as low as 0.01%, depending on whether they are foam, stabilizers or surfactants. The invention further relates to a method of marking a substrate, support, or object by projecting onto a surface of said substrate, support, or object of an ink composition by the deviated continuous jet technique, wherein the projected ink composition is the ink composition according to the invention as described above. Generally, prior to the projection of the ink composition, the surface of the substrate, substrate, or object is not subject to any surface treatment other than simple cleaning. In other words, the surface is not subjected to any activation treatment. The invention also relates to a substrate, support, or object provided with a marking obtained by drying, and / or absorption in the substrate, support, or object, of the ink composition according to the invention.
    [0027] This substrate may be porous or non-porous.
    [0028] This substrate may be made of metal, for example aluminum, steel; glass ; ceramic; a material containing cellulose such as paper, possibly coated or glossy, cardboard or wood; an organic polymer, in particular a thermoplastic polymer, preferably chosen from PVC, PET, polyolefins, such as polyethylenes (PE) and polypropylenes (PP); Poly (Methyl methacrylate) PMMA also called "Plexiglas"; Fabric ; or any other non-porous or porous substance, or a composite of many of the foregoing materials. A preferred substrate is a polyolefin substrate, for example polyethylene or polypropylene. The substrate, carrier or object may be a package or a container, such as a bottle, vial or tray; a plug ; a pipe or cable; preferably a polyolefin, for example a polyethylene or a polypropylene.
    [0029] The substrate may have any color. It can be so white, of light color or black, of dark color. The color of the ink composition, and thus in particular the color of the pigment or dye of the ink composition, is generally chosen so that the marking obtained with the ink composition has a color which differs from the color of the substrate or, more exactly, the color of the surface of the substrate provided with the marking. As already indicated above, a black or dark-colored ink composition, which gives a black or dark color marking, is particularly suitable for marking white or light-colored substrates.
    [0030] On the other hand, an opaque, preferably white or light-colored ink composition which gives a white or light-colored marking is particularly suitable for marking black or dark-colored substrates such as cables or pipes.
    [0031] The substrate, or rather the surface of the substrate, provided with the marking, may have any shape, even a complex one, it may be in particular a curved surface, for example of the surface of a package or container, such as a bottle, a bottle, or a tray, or the surface of a plug, or the surface of a pipe or cable. Marks, prints of excellent quality and resistant are obtained on all substrates, even very little porous, especially on polyolefin substrates, for example polyethylene, even complex shapes such as packaging or containers such as bottles bottles or trays; or caps; or pipes or cables; a polyolefin, for example a polyethylene or a polypropylene. The invention will be better understood on reading the following description of embodiments of the invention, given by way of illustrative and non-limiting examples. EXAMPLES The following ink compositions according to the invention were prepared by mixing the products mentioned in Table I below, in the proportions indicated. The viscosities and the conductivities of the inks obtained are also given in Table I below.
    [0032] Table I Constituents Example No. 1 Ex. Ex. Ex. Ex. Ex. Ex. Ex. Ex. E x. No. 9 Ex. Ex. (Percentages by weight) No. 2 No. 3 No. 4 No. 5 No. 6 No. 7 No. 8 No. 10 No. 11 Methyl ethyl ketone 72.5 58 53.8 54 62 56.8 53.8 53.8 53.8 57.8 57.8 Dowanoi PMA® 3 3 3 4 4 3 3 3 3 3 Polyester resin 12.4 10 9 10 13 10 7 7 7.9 9 10 , 1 (Toyobo Vylon GK 250®) Rosin Resin 8 8 7 8 10.6 8.4 5.5 3.6 4.3 (Bremasin 1380® from Kraemer®) Polyol Resin (Synthetic resin 6 4 8 4,4,6,6 8,6 5,4 3,6 SK of Evonik®) Dispersion of TiO2 to 65 in 20-methyl-ethyl ketone Solvent Black 27 6 (Black Neozapon®) X51) BYK UV3500® 0.7 Potassium thiocyanate 0.4 1 1.2 1 1 1.2 1.2 1.2 1.2 1.2 1.2 Viscosity (mPa $) 4.35 4.03 4 , 84 5.04 4.42 4.32 3.97 3.9 4.89 3.73 4.2 3033572 The ink of Example 1 is a black ink because it contains Solvent Black 27. The ink of Examples 2 to 11 is a white opaque ink because it contains TiO 2. The black ink of Example 1 was deposited using Markem-Imaje® 9040 printers, which use the deviated continuous jet printing technique, on polyethylene bottles. On identical bottles, made of polyethylene (HDPE) and polypropylene, the Markem-Imaje® comparative black ink referenced 5513 was deposited using Markem-Imaje® 9040 printers. This ink serves as a control, a comparative because it is currently used for this application for marking vials made of polyethylene or polypropylene. This comparative ink does not comprise any polyester resin, nor does it comprise rosin resin or polyol resin.
    [0033] After 24 hours of drying, the markings on the polyethylene bottles were successively: - rubbed with the finger by making round trip (AR); soaked for a few minutes in water and the same rub test was repeated up to 30 rounds; 20 - rubbed with a cotton soaked in ethanol by making up to 30 round trips; subject to the "Scotch" test as already described above. The white inks of Examples 2 to 11 were deposited using Markem-Imaje® 9040 printers, which utilize the technique of continuous deviated jet printing, on dark colored polyethylene cables and others. dark colored polypropylene racks. On identical cables, made of polyethylene (HDPE) and polypropylene, Markem-Imaje® comparative white ink 5137 was deposited using Markem-Imaje® 9040 printers. This ink serves as a control, a comparative, because it is currently used for this application of marking cables or tubes in polyethylene or polypropylene. This comparative ink does not comprise a polyester resin, nor does it comprise rosin resin or polyol resin. After 24 hours of drying, the markings on the polyethylene cables and polypropylene supports were successively: - rubbed on the finger by making 30 round trip; soaked for a few minutes in water and the same rub test was repeated up to 30 rounds; 10 - rubbed with a cotton soaked in ethanol by performing up to 30 round trips (AR); If the marking is already erased by making a round-trip number of less than 30, the number of round-trips (AR), for example 3, 5, 8, or 10, is then noted so that the marking is erased. subject to the "Scotch" test as already described above. The results are summarized in Table II below: Table II. TESTED INKS Example Ex. Ex No. 2 Ex. No. 3 Ex. No. 4 Ex No. 5 Ex No. 6 Ex. No. 7 Ex No. 8 Ex No. 9 Ex No. 10 Ex No. 11 Ex. Neither Comparative Comparative 1: Ink 2: 5513 Ink 5137 HDPE Friction 5 5 5 5 5 5 5 5 5 5 5 5 5 bottle or cable Scotch 4 5 0 3 2 0.5 0.5 0.5 2 2 3 3 0 Friction Ethanol 5 0 8AR 5 AR 8 AR 10AR 5AR 3 AR 4 AR 30 AR 5 AR 10 AR 10AR Friction 5 5 5 5 5 5 5 5 5 5 5 5 5 H20 Support Friction 5 5 5 5 5 5 5 5 5 5 5 5 5 PP Scotch Tape Tape Test 4 5 0 3 3 0 0.5 3 3 2 2 2 0 Friction 5 5 5 5 5 5 5 5 5 5 5 5 5 H20 The test results were scored on a rating scale of from 1 to 5. Note: 5 = unchanged marking 4 = 20% of the damaged marking 3 = 50% of the marking damaged or erased 2 = 80% of the marking damaged or erased 1 = Marking completely erased Or number of round-trips ( AR) so that the marking is erased when the marking is already erased by a round-trip number of less than 30.
    [0034] The black ink of Example 1 according to the invention shows better performances than the comparative black ink 5513 and the white inks of Examples 2 to 11 according to the invention show better performances than the comparative white ink. 5137.
    权利要求:
    Claims (28)
    [0001]
    REVENDICATIONS1. An ink composition for continuous flow jet printing, liquid at room temperature, comprising: a) a solvent comprising, preferably consisting of, one or more organic solvent (s) and optionally some water ; b) a binder, comprising at least one polyester resin prepared by polymerization of terephthalic acid, isophthalic acid, neopentyl glycol, and ethylene glycol; C) optionally, one or more dye (s) and / or pigment (s).
    [0002]
    An ink composition according to claim 1 which is free of halogenated compounds.
    [0003]
    An ink composition according to claim 1 or 2, further comprising a resin derived from rosin.
    [0004]
    The ink composition according to any one of claims 1 to 3, further comprising a polyol resin. 20
    [0005]
    An ink composition according to any one of the preceding claims which comprises from 0.1% to 30% by weight, preferably from 5% to 20% by weight, of the total weight of the ink composition, the polyester resin. 25
    [0006]
    An ink composition according to claim 3, which comprises from 0.1% to 20% by weight, preferably from 1% to 15% by weight, of the total weight of the ink composition, of the rosin-derived resin. .
    [0007]
    The ink composition of claim 4 which comprises from 0.1% to 25% by weight, preferably from 2% to 10% by weight, of the total weight of the ink composition of the polyol resin. 3033572 31
    [0008]
    An ink composition according to claims 1, 3, and 4, wherein the binder comprises both the polyester resin prepared by polymerization of terephthalic acid, isophthalic acid, neopentyl glycol, and ethylene glycol, the resin derived from rosin, and the polyol resin.
    [0009]
    The ink composition according to claim 8, wherein the binder is the polyester resin, the rosin-derived resin and the polyol resin, preferably in the following proportions by weight based on the total weight of the binder: % to 60% of the polyester resin, 20% to 50% of the resin derived from rosin, and 15% to 40% of the polyol resin.
    [0010]
    An ink composition according to any one of the preceding claims, comprising less than 10% by weight, preferably less than 5% by weight, more preferably less than 1% by weight, and more preferably 0% by weight. water, based on the total weight of the ink composition.
    [0011]
    An ink composition according to any of the preceding claims, wherein the solvent is at least 20% by weight of the total weight of the ink composition, preferably the solvent is from 30% to 90% by weight more preferably from 60% to 80% by weight of the total weight of the ink composition.
    [0012]
    An ink composition according to any one of the preceding claims, wherein said organic solvent compound (s) comprises (include) a major proportion by weight, based on the total weight of the solvent. , one or more volatile organic solvent compound (s), and a minor proportion by weight, based on the total weight of the solvent, of one or more solvent compound (s) ) non-volatile organic (s); preferably, the solvent consists of one or more volatile organic solvent (s) compound (s). 30
    [0013]
    An ink composition according to any one of the preceding claims, wherein the solvent comprises a major amount by weight, based on the total weight of the solvent, preferably consists of one or more compound (s). solvent (s) chosen from ketones of 3 to 10 carbon atoms, such as acetone, butanone (methyl-ethyl-ketone or MEK), pentan-2-one (methyl-propyl-ketone), methyl-3-butanone-2 (methyl-isopropyl ketone) and methyl-4-pentanone-2 (methyl isobutyl ketone or MIK).
    [0014]
    The ink composition according to claim 13, further comprising one or more other solvent (s) other than the compound (s) ketone (s) in a minor amount by weight relative to the total weight of the solvent. , for example in an amount of 0.1% to 20% by weight, preferably 5% to 15% by weight relative to the total weight of the solvent.
    [0015]
    An ink composition according to any of the preceding claims, wherein said one or more dyes and / or pigment (s) is (are) selected from dyes and pigments known as " CI Solvent Dyes "and" CI Pigments "such as Solvent Black 29 CI, Solvent Black 27 CI, Solvent Black 7 IC, Solvent Black 28 CI, Solvent Black 35 IC, Solvent Blue 45 IC, Solvent Blue 70 IC, Solvent IC Red 124, dispersions of Pigment Blue 60 or Pigment Blue 15, Pigment Black 7, Pigment White 6; fluorescent dyes; and optical brighteners.
    [0016]
    An ink composition according to any one of the preceding claims, which is black or dark in color.
    [0017]
    An ink composition according to any one of claims 1 to 15, which is opaque, preferably white or light in color.
    [0018]
    An ink composition according to any one of the preceding claims, wherein the total amount of dye (s) and / or pigment (s) is from 0.05% to 25% by weight, preferably from 1% to 20% by weight, more preferably from 3% to 10% by weight, of the total weight of the ink composition. 3033572 33
    [0019]
    Ink composition according to any one of the preceding claims, further comprising one or more plasticisers.
    [0020]
    An ink composition according to any one of the preceding claims, which has an electrical conductivity greater than 300 μS / cm at 20 ° C, preferably greater than or equal to 500 μS / cm at 20 ° C.
    [0021]
    The ink composition according to any one of the preceding claims, further comprising at least one conductivity salt, preferably selected from water insoluble conductivity salts.
    [0022]
    22. Composition according to claim 21, in which the salt (s) of conductivity is (are) present in a proportion of at least 0.05% by weight, preferably at a rate of 0.1%. at 20% by weight, more preferably from 0.1% to 10% by weight, more preferably from 0.1% to 5% by weight, of the total weight of the ink composition.
    [0023]
    An ink composition according to any one of the preceding claims, further comprising one or more additives selected from antifoam agents; chemical stabilizers; UV stabilizers; surfactants; agents inhibiting corrosion by salts; bactericides, fungicides and biocides; and pH buffers.
    [0024]
    24. A method of marking a substrate, support or object by projecting onto a surface of said substrate, support, or object of an ink composition by the deviated continuous jet technique, wherein the projected ink composition is the ink composition according to any one of claims 1 to 23.
    [0025]
    25. The method of claim 24, wherein prior to the spraying of the ink composition, the surface of the substrate, substrate, or object is not subject to any surface treatment other than simple cleaning. 3033572 34
    [0026]
    26. Substrate, carrier, or object having a mark obtained by drying, and / or absorption in the substrate, carrier, or object, of the ink composition according to any one of claims 1 to 23.
    [0027]
    27. Substrate, support or object according to claim 26 which is made of metal, for example aluminum, steel; glass ; ceramic; a material containing cellulose such as paper, possibly coated or glossy, cardboard or wood; an organic polymer, especially a thermoplastic polymer, preferably selected from PVC, PET, polyolefins, such as polyethylenes (PE), and polypropylenes (PP); Poly (Methyl methacrylate) PMMA also called "Plexiglas"; Fabric ; or any other non-porous or porous substance, or a composite of many of the foregoing materials.
    [0028]
    28. The substrate, carrier, or article of claim 27, which is a package or container, such as a bottle, vial, or tray; a plug ; a pipe or cable; preferably a polyolefin, for example a polyethylene or a polypropylene.
    类似技术:
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    同族专利:
    公开号 | 公开日
    EP3067397A1|2016-09-14|
    CN105968953A|2016-09-28|
    US20160264797A1|2016-09-15|
    FR3033572B1|2019-05-10|
    EP3067397B1|2020-12-30|
    US10072165B2|2018-09-11|
    CN105968953B|2021-04-09|
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    FR2912414B1|2007-02-13|2012-09-28|Imaje Sa|INK COMPOSITION FOR INKJET PRINTING.|
    JP5219140B2|2008-10-24|2013-06-26|東洋紡株式会社|Low-temperature conductive paste for plating and electrical wiring using the same|US20200079967A1|2017-04-14|2020-03-12|Videojet Technologies Inc.|Fast dry ink composition for continuous inkjet applications|
    CN107868510A|2017-11-29|2018-04-03|苏州世华新材料科技有限公司|A kind of one-component black matte dielectric ink and preparation method thereof|
    WO2019157482A1|2018-02-12|2019-08-15|Sun Chemical Corporation|Smear resistant ink composition|
    KR20200125635A|2018-02-26|2020-11-04|스미또모 가가꾸 가부시키가이샤|Colored resin composition|
    KR20200126977A|2018-03-08|2020-11-09|사카타 인쿠스 가부시키가이샤|Continuous inkjet ink composition|
    法律状态:
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    2021-03-30| PLFP| Fee payment|Year of fee payment: 7 |
    优先权:
    申请号 | 申请日 | 专利标题
    FR1552078|2015-03-13|
    FR1552078A|FR3033572B1|2015-03-13|2015-03-13|INK COMPOSITION FOR CONTINUOUS JET PRINTING IN PARTICULAR ON ORGANIC POLYMER SUBSTRATES.|FR1552078A| FR3033572B1|2015-03-13|2015-03-13|INK COMPOSITION FOR CONTINUOUS JET PRINTING IN PARTICULAR ON ORGANIC POLYMER SUBSTRATES.|
    US15/067,793| US10072165B2|2015-03-13|2016-03-11|Ink composition for deflected continuous ink jet printing notably on organic polymers substrates|
    EP16159785.1A| EP3067397B1|2015-03-13|2016-03-11|Ink composition for deflected continuous ink jet printing notably on organic polymers substrates|
    CN201610144990.5A| CN105968953B|2015-03-13|2016-03-14|Ink composition for deflected continuous ink jet printing on organic polymeric substrates|
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